Alok,
Let's do these steps, execute Tcode in CRM, CRM_SERVICE_CO_CHAR, select all check boxes under 'objects to be replicated', and execute (make sure RFC destination of ECC is there), go to ECC, check your controlling integration scenario, I am thinking you have defined single object controlling, create your Service Order in CRM via follow up, then release your service order and check whether internal order is created.
Thanks
Kiran Katla